23,587 research outputs found
An investigation of the information propagation and entropy transport aspects of Stirling machine numerical simulation
Aspects of the information propagation modeling behavior of integral machine computer simulation programs are investigated in terms of a transmission line. In particular, the effects of pressure-linking and temporal integration algorithms on the amplitude ratio and phase angle predictions are compared against experimental and closed-form analytic data. It is concluded that the discretized, first order conservation balances may not be adequate for modeling information propagation effects at characteristic numbers less than about 24. An entropy transport equation suitable for generalized use in Stirling machine simulation is developed. The equation is evaluated by including it in a simulation of an incompressible oscillating flow apparatus designed to demonstrate the effect of flow oscillations on the enhancement of thermal diffusion. Numerical false diffusion is found to be a major factor inhibiting validation of the simulation predictions with experimental and closed-form analytic data. A generalized false diffusion correction algorithm is developed which allows the numerical results to match their analytic counterparts. Under these conditions, the simulation yields entropy predictions which satisfy Clausius' inequality
Real fluid properties of normal and parahydrogen
Computer program calculates the real fluid properties of normal or parahydrogen using a library of single function calls without initial estimates. Accurate transport and thermodynamic properties of molecular hydrogen are needed for advanced propulsion systems
Using giant scarlet runner bean embryos to uncover regulatory networks controlling suspensor gene activity.
One of the major unsolved issues in plant development is understanding the regulatory networks that control the differential gene activity that is required for the specification and development of the two major embryonic regions, the embryo proper and suspensor. Historically, the giant embryo of scarlet runner bean (SRB), Phaseolus coccineus, has been used as a model system to investigate the physiological events that occur early in embryogenesis-focusing on the question of what role the suspensor region plays. A major feature distinguishing SRB embryos from those of other plants is a highly enlarged suspensor containing at least 200 cells that synthesize growth regulators required for subsequent embryonic development. Recent studies have exploited the giant size of the SRB embryo to micro-dissect the embryo proper and suspensor regions in order to use genomics-based approaches to identify regulatory genes that may be involved in controlling suspensor and embryo proper differentiation, as well as the cellular processes that may be unique to each embryonic region. Here we review the current genomics resources that make SRB embryos a compelling model system for studying the early events required to program embryo development
A Palladium-Catalyzed Vinylcyclopropane (3 + 2) Cycloaddition Approach to the Melodinus Alkaloids
A palladium-catalyzed (3 + 2) cycloaddition of a vinylcyclopropane and a β-nitrostyrene is employed to rapidly assemble the cyclopentane core of the Melodinus alkaloids. The ABCD ring system of the natural product family is prepared in six steps from commercially available materials
Crystal structure prediction using the Minima Hopping method
A structure prediction method is presented based on the Minima Hopping
method. Optimized moves on the configurational enthalpy surface are performed
to escape local minima using variable cell shape molecular dynamics by aligning
the initial atomic and cell velocities to low curvature directions of the
current minimum. The method is applied to both silicon crystals and binary
Lennard-Jones mixtures and the results are compared to previous investigations.
It is shown that a high success rate is achieved and a reliable prediction of
unknown ground state structures is possible.Comment: 9 pages, 6 figures, novel approach in structure prediction, submitted
to the Journal of Chemical Physic
Stationary generalized Kerr-Schild spacetimes
In this paper we have applied the generalized Kerr-Schild transformation
finding a new family of stationary perfect-fluid solutions of the Einstein
field equations. The procedure used combines some well-known techniques of null
and timelike vector fields, from which some properties of the solutions are
studied in a coordinate-free way. These spacetimes are algebraically special
being their Petrov types II and D. This family includes all the classical
vacuum Kerr-Schild spacetimes, excepting the plane-fronted gravitational waves,
and some other interesting solutions as, for instance, the Kerr metric in the
background of the Einstein Universe. However, the family is much more general
and depends on an arbitrary function of one variable.Comment: 21 pages, LaTeX 2.09. To be published in Journal of Mathematical
Physic
Collaborative Filtering via Group-Structured Dictionary Learning
Structured sparse coding and the related structured dictionary learning
problems are novel research areas in machine learning. In this paper we present
a new application of structured dictionary learning for collaborative filtering
based recommender systems. Our extensive numerical experiments demonstrate that
the presented technique outperforms its state-of-the-art competitors and has
several advantages over approaches that do not put structured constraints on
the dictionary elements.Comment: A compressed version of the paper has been accepted for publication
at the 10th International Conference on Latent Variable Analysis and Source
Separation (LVA/ICA 2012
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